Advanced Search
CHEN Hong-shan, LI Shu-ben, NIU Jian-zhong. AnMO Study on Methane Activation over Tetrahedral [WO4][J]. Nuclear Physics Review, 2002, 19(2): 209-212. DOI: 10.11804/NuclPhysRev.19.02.209
Citation: CHEN Hong-shan, LI Shu-ben, NIU Jian-zhong. AnMO Study on Methane Activation over Tetrahedral [WO4][J]. Nuclear Physics Review, 2002, 19(2): 209-212. DOI: 10.11804/NuclPhysRev.19.02.209
shu

AnMO Study on Methane Activation over Tetrahedral WO4

    Graphical Abstract
    • Abstract
  • By using ab initio DFT method, the metal species formed over the silica surface on Na-W-Mn/SiO 2are optimized, the electronic structure of the catalyst and the activation process of methane is studied. The silica support in the catalyst exists as α-cristobalite and its (111) face exposes preferentially to the surface. Over the surface of α-cristobalite, tungsten existed as monografted tetrahedral \ at the optimal loading amount, and manganese exists in monografted sites or oxide clusters...
    • FullText(HTML)
  • loading
    • References (0)
    • Related Articles
  • Supplements (0)

Catalog

    /

    DownLoad:  Full-Size Img  PowerPoint
    Return
    Return