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辐照前处理木质纤维素的研究进展

Research Progress in Radiation Pretreatments of Lignocellulose

  • 摘要: 本文对几种主要的辐照前处理木质纤维素方法的效果和特点进行较为全面的比较和总结,旨在阐述微波、紫外线、γ射线、X射线、电子束、离子束等方式辐照前处理木质纤维素对其结构改变的机理尤其重点探讨了重离子辐照前处理引起木质纤维素同质异形体(Iα → Iβ)的转换机制。木质纤维素结晶度与酶消化率呈强相关性,重离子辐照前处理可使木质纤维素中木质素和半纤维素部分破坏,导致其相对结晶度增加,从而增强了纤维素酶与木质纤维素的可及度,提高了酶解产率。因而,通过适当剂量的重离子辐照前处理可以显著提高酶对木质纤维素的生物转化效率和还原糖的产量,这为辐照前处理提高木质纤维素的综合利用提供了理论指导。

     

    Abstract: In this paper, the effects and characteristics of several main irradiated pretreatment methods for lignocellulose are compared and summarized comprehensively. The mechanism of lignocellulose pretreated by microwave, ultraviolet, gamma ray, X ray, electron beam and ion beam were expounded. In particular, the transformation of polymorphys in lignocellulose (Iα → Iβ) caused by pretreatment with heavy ion beams irradiation was discussed. The crystallinity index of lignocellulose was strongly correlated with enzyme digestibility. The pretreatment of heavy ion beam radiation can destroy the lignin and hemicellulose partially, resulting in an increase in its relative crystallization, which enhances the accessibility of cellulase and lignocellulose, also increase the enzymatic hydrolysis yield. Therefore, the biotransformation efficiency of enzyme to lignocellulose and the yield of reducing sugar can be significantly improved at the appropriate dose of heavy ion beam radiation pretreatment, which provides the theoretical guidance for radiation pretreatment to improve the comprehensive utilization of lignocellulose.

     

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