丙酮分子在355nm激光作用下的异构化过程

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丙酮分子在355nm激光作用下的异构化过程

胡湛, 金明星, 刘航, 丁大军

文章导航 > 原子核物理评论 > 2002 > 19(2): 188-191

胡湛, 金明星, 刘航, 丁大军. 丙酮分子在355nm激光作用下的异构化过程[J]. 原子核物理评论, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

引用本文:

胡湛, 金明星, 刘航, 丁大军. 丙酮分子在355nm激光作用下的异构化过程[J]. 原子核物理评论, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

HU Zhan, JIN Ming-xing, LIU Hang, DING Da-jun. Isomerization Processes of Acetone Induced by 355 nm Laser[J]. Nuclear Physics Review, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

Citation:

HU Zhan, JIN Ming-xing, LIU Hang, DING Da-jun. Isomerization Processes of Acetone Induced by 355 nm Laser[J]. Nuclear Physics Review, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

丙酮分子在355nm激光作用下的异构化过程

doi: 10.11804/NuclPhysRev.19.02.188

吉林大学原子与分子物理研究所

Isomerization Processes of Acetone Induced by 355 nm Laser

(Institute of Atomic and Molecular Physics; Jilin University; Changchun 130023; China);

摘要: 阐述了在 35 5nm激光作用下超声分子束中丙酮分子的两种异构化过程 ,其中一种为此实验条件下首次观测到的丙酮到丙烯醇的异构 .对两种异构化反应分别给出了过程描述.使用氘代丙酮对异构产物的可能性进行了验证 .并通过中间产物的实验结果进一步说明异构过程. Two isomerization processes of acetone molecule in supersonic beams induced by 355 nm laser are discussed. It is the first time to observe the isomerization from acetone to ally alcohol in this experimental condition. The isomerization process is suggested and verified by time of flight mass spectrum experiments of deuterated acetone and a transient product.
- 丙酮 /
- 异构化 /
- 反射式飞行时间质谱
Abstract: Two isomerization processes of acetone molecule in supersonic beams induced by 355 nm laser are discussed. It is the first time to observe the isomerization from acetone to ally alcohol in this experimental condition. The isomerization process is suggested and verified by time of flight mass spectrum experiments of deuterated acetone and a transient product.
- acetone /
- isomerization /
- reflectron time-of-flight mass spectrum

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丙酮分子在355nm激光作用下的异构化过程

doi: 10.11804/NuclPhysRev.19.02.188

吉林大学原子与分子物理研究所

收稿日期: 1900-01-01
修回日期: 1900-01-01
刊出日期: 2002-06-20

关键词:

反射式飞行时间质谱

摘要: 阐述了在 35 5nm激光作用下超声分子束中丙酮分子的两种异构化过程 ,其中一种为此实验条件下首次观测到的丙酮到丙烯醇的异构 .对两种异构化反应分别给出了过程描述.使用氘代丙酮对异构产物的可能性进行了验证 .并通过中间产物的实验结果进一步说明异构过程. Two isomerization processes of acetone molecule in supersonic beams induced by 355 nm laser are discussed. It is the first time to observe the isomerization from acetone to ally alcohol in this experimental condition. The isomerization process is suggested and verified by time of flight mass spectrum experiments of deuterated acetone and a transient product.

English Abstract

胡湛, 金明星, 刘航, 丁大军. 丙酮分子在355nm激光作用下的异构化过程[J]. 原子核物理评论, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

引用本文:

胡湛, 金明星, 刘航, 丁大军. 丙酮分子在355nm激光作用下的异构化过程[J]. 原子核物理评论, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

HU Zhan, JIN Ming-xing, LIU Hang, DING Da-jun. Isomerization Processes of Acetone Induced by 355 nm Laser[J]. Nuclear Physics Review, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

Citation:

HU Zhan, JIN Ming-xing, LIU Hang, DING Da-jun. Isomerization Processes of Acetone Induced by 355 nm Laser[J]. Nuclear Physics Review, 2002, 19(2): 188-191. doi: 10.11804/NuclPhysRev.19.02.188

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